By Katsuhiko Ariga;Toyoki Kunitake

This publication describes "supramolecular chemistry" from its uncomplicated innovations to the most recent advancements. It starts via treating molecular attractiveness chemistry together with crown ethers, cyclodextrines, and calixarenes. Molecules with fascination shapes and capabilities reminiscent of fullerenes, carbon nanotubes, dendrimers, rotaxane, and catenane, and molecular assemblies similar to bilayers and LB movies also are defined. Thereafter purposes of supermolecules to nanotechnology are brought with many examples of molecular units. The final a part of the ebook describes organic supermolecules and their mimics, together with ion channels, sign transduction, photosynthetic machines, average and synthetic enzymes, catalytic antibodies, and ribozymes.

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Am. Chem. , 118, 9545 (1996) K. Ariga, A. Kamino, X. Cha, T. Y. Sasaki, K. Kurihara, T. Kunitake, “Self-Assembled Miltifunctional Receptors for Nucleotides at the Air–Water Interface”, J. Am. Chem. , 114, 10994 (1992) K. Taguchi, K. Ariga, T. Kunitake, “Multi-Site Recognition of Flavin Adenine Dinucleotide by Mixed Monolayers on Water”, Chem. , 701 (1995) K. Ariga, A. Kamino, H. Koyano, T. Kunitake, “Recognition of Aqueous Flavin Mononucleotide on the Surface of Binary Monolayers of Guanidinium and Melamine Amphiphiles”, J.

The isomers vary in terms of the orientations of their phenol groups: (a) has a cone structure with all of the phenols pointing to the same direction; (b) has a partial cone structure with one phenol pointing in a different direction to the others; (c) has a 1,3-alternate structure with neighboring phenols pointing in opposite directions. These isomeric hosts have different selectivities for metal ion inclusion in the upper cavity and the lower cavity. Of course, changing the number of phenol residues alters the guest size appropriate for effective inclusion.

J. Szejtli, “Introduction and General Overview of Cyclodextrin Chemistry”, Chem. , 98, 1743 (1998) 42. V. Rekharsky, Y. Inoue, “Complexation Thermodynamics of Cyclodextrins”, Chem. , 98, 1875 (1998) 43. A. Ueno, T. Kuwabara, A. Nakamura, F. Toda, “A Modified Cyclodextrin as a Guest Responsive Color-Change Indicator”, Nature, 356, 136 (1992) 44. S. Minato, T. Osa, M. Morita, A. Nakamura, H. Ikeda, F. Toda, A. Ueno, “Intramolecular Excimer Formation and Molecular Recognition of Modified Cyclodextrins Appended by Two Naphthalene Rings”, Photochem.

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