By Ben Qiu, Shilun Qiu, Teng Ben
Porous fabrics with ultrahigh floor region are of serious curiosity for power functions in power garage and environmental remediation. Porous Polymers describes the numerous contemporary growth within the improvement of alternative porous frameworks, with a specific specialize in the connection among constitution layout, synthesis technique and houses. The ebook starts off with an advent to porous fabrics and their services via chapters the layout of porous polymers, synthesis tools of porous polymers (reversible tools, irreversible equipment, copolymerization tools and self-polymerization methods); characterisation of porous polymer constructions and post-synthesis thoughts of porous polymers (lithiation, sulphonation, carbonization, grafting). particular chapters then element various porous fabrics platforms resembling conjugated microporous polymers (CMPs); covalent natural frameworks (COFs); hyper-crosslinked polymers (HCPs); polymers of intrinsic microporosity (PIMs); and porous fragrant frameworks (PAFs). Written by way of energetic researchers within the box, the e-book presents a entire assessment of alternative porous polymer structures for researchers and graduate scholars in chemistry and fabrics technology engaged on novel fabrics and people drawn to the power and environmental purposes
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Additional resources for Porous polymers : design, synthesis and applications
Ren, M. Guo, K. Cai, X. Jing, X. Gao and G. Zhu, Adv. , 2013, 25, 6619. Copyright 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. 1 Polymers with Intrinsic Microporosity Polymers with intrinsic microporosity, abbreviated as PIMs, were developed for the first time by McKeown and Budd. 54b,112 The principle behind the synthesis of PIMs employs non-reversible condensation reactions to form polymers. These polymers cannot eﬃciently fill the space and pack together due to components that are rigid and ladder-like, and thus force the backbone of the polymer to twist or turn.
I. Benin, N. W. Ockwig, M. O’Keeﬀe, A. J. Matzger and O. M. Yaghi, Science, 2005, 310, 1166. Copyright 2005, American Association for the Advancement of Science. Chemical Synthesis of Porous Polymers 47 COF-1 is the simplest of the compounds among covalent organic frameworks. It is formed by the elimination of water in the self-condensation of benzene-1,4-diboronic acid. On the other hand, COF-5 is synthesized by employing the same type of condensation reaction between benzene-1,4diboronic acid and HHTP, forming a BC2O2-linking ring.
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