By Martin Moeller, Krzysztof Matyjaszewski

The growth in polymer technological know-how is published in basically all chapters of Polymer technological know-how: A complete Reference. In quantity 1, edited by means of Khokhlov and Kremer, this can be mirrored within the stronger realizing of the homes of polymers in resolution, in bulk and in limited events equivalent to in skinny movies. quantity 2, edited through Spiess, Hashimoto and Takenaka, addresses new characterization suggestions, akin to excessive answer optical microscopy, scanning probe microscopy and different approaches for floor and interface characterization. quantity three, edited via Coates and Sawamoto, provides the good development completed in distinct artificial polymerization innovations for vinyl monomers to manage macromolecular structure: the improvement of metallocene and post-metallocene catalysis for olefin polymerization, new ionic polymerization methods, and atom move radical polymerization, nitroxide mediated polymerization, and reversible addition-fragmentation chain move structures because the commonly used controlled/living radical polymerization equipment. quantity four, edited through Penczek and Grubbs, is dedicated to kinetics, mechanisms and purposes of ring establishing polymerization of heterocyclic monomers and cycloolefins (ROMP), in addition to to varied much less universal polymerization thoughts. Polycondensation and non-chain polymerizations, together with dendrimer synthesis and numerous "click" techniques, are lined in quantity five, edited by way of Schmidt and Ueda. quantity 6, edited via Mueller and Wooley, makes a speciality of numerous facets of managed macromolecular architectures and delicate nano-objects together with hybrids and bioconjugates. a number of the achievements could haven't been attainable with no new characterization recommendations like AFM that allowed direct imaging of unmarried molecules and nano-objects with a precision on hand just recently. a wholly new point in polymer technology is predicated at the blend of bottom-up equipment resembling polymer synthesis and molecularly programmed self-assembly with top-down structuring corresponding to lithography and floor templating, as provided in quantity 7, edited by means of Kumacheva and Russell. It encompasses polymer and nanoparticle meeting in bulk and below restricted stipulations or motivated by way of an exterior box, together with skinny motion pictures, inorganic-organic hybrids, or nanofibers. quantity eight, edited via Muellen and Ober, expands those suggestions targeting functions in complicated applied sciences, e.g. in digital and facilities on mix with best down process and sensible houses like conductivity. one other kind of performance that's of swiftly expanding value in polymer technology is brought in quantity nine, edited via Langer and Tirrell. It offers with quite a few facets of polymers in biology and drugs, together with the reaction of residing cells and tissue to the touch with biofunctional debris and surfaces. The final quantity 10, edited via Hoefer, Hickner and McGrath, is dedicated to the scope and strength supplied through environmentally benign and eco-friendly polymers, in addition to energy-related polymers. They speak about new applied sciences wanted for a sustainable financial system in our international of constrained assets. universal to all techniques in Polymer technology: A entire Reference is getting to know an expanding complexity of the polymer fabrics constitution wanted for a transformation in concentration from commodities to fabrics for numerous complicated functions, relating to strength, setting, and biomedicine.

  • Provides huge and in-depth assurance of all elements of polymer technological know-how from synthesis/polymerization, houses, and characterization tools and strategies to nanostructures, sustainability and effort, and biomedical makes use of of polymers
  • Provides a definitive resource for these coming into or discovering during this quarter through integrating the multidisciplinary elements of the technological know-how into one designated, updated reference work
  • Electronic model has entire cross-referencing and multi-media components
  • Volume editors are international specialists of their box (including a Nobel Prize winner)
  • 269 chapters masking all points of polymer technology from synthesis, characterization, homes and nanostructures to biomedical makes use of, sustainability and effort functions

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Additional info for Polymer Science: A Comprehensive Reference, 10 Volume Set

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Very recently, a series of studies have focused on the prepara­ tion of tadpole polymers using ATRP121–123 or ring-opening polymerization124 combined with click chemistry. Cyclic PS as the head and a linear poly(N-isopropylacrylamide) as the tail121 and cyclic poly(ethylene gycol) with two linear poly (N-isopropylacrylamide) chains122 were synthesized by the combination of living radical polymerization and click chemis­ try. 4(ii) Bicyclic and polycyclic polymers Bicyclic polymer topologies, which include structures such as eight-shaped, manacle, and catenates, were also prepared using various approaches.

16 Topology | Synthesis and Properties of Macrocyclic Polymers Ring reopening H+ Figure 4 AFM images of cyclic combs after treatment in acidic media. ; Deffieux, A. 93 © Copyright 2010 from American Chemical Society. 79 have made cyclic poly(styrene-b­ chloroethylvinyl ether) copolymers from an anionically pre­ pared α-styrenyl-ω-acetal PS. They converted the acetal to an α-iodoether function in the presence of trimethylsilyl iodide and polymerized the chloroethylvinyl ether monomer cationi­ cally.

Then, the growing chain end is activated at the end of the polymerization by a catalyst to allow its reaction under dilute conditions with the other poly­ mer end function, allowing the ring to close. This strategy is outlined in Scheme 8 for the preparation of an α-styrenyl poly(2-chloroethylvinyl ether) chain by cationic polymeriza­ tion of 2-chloroethylvinyl ether. 80 In these conditions, the styrenic double bond is unaffected. Cyclization is performed at –10 °C by dropwise addition of the living polymer to a solu­ tion of SnCl4 in toluene: SnCl4 activates the α-iodoether terminus and causes its addition to a styrenic double bond.

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