By Richard F. Heck

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Taylor, and D. T. Thompson, "Reactions of Transition Metal Complexes," Elsevier, Amsterdam, 1968. J. P. Collman, Reactions of coordinated ligands. Transition Metal Chem. 2, 1 (1966). J. P. Collman, Patterns of organometallic reactions. Accounts Chem. Res. 1, 136 (1968). M. L. H. Green, "Organometallic Compounds," Vol. II. Methuen, London, 1968. R. F. Heck, Addition reactions. Advan. Organometal. Chem. 4, 243 (1966). R. F. Heck, Addition reactions of metal complexes. Accounts Chem. Res. 2, 10 (1969).

A. Cotton and G. Wilkinson, "Advanced Inorganic Chemistry," 3rd ed. Wiley (Interscience), New York, 1972. J. O. " Benjamin, New York, 1964. R. F. , Homogeneous Catalysis: Industrial Applications and Implications, No. 70. Advan. Chem. , 1968. M. D. Rausch, History and development of organo-transition metal chemistry. Advan. Chem. Ser. 62, 486 (1966). Chapter II The Formation of Hydrogen and Carbon Bonds to Transition Metals Transition metal hydrides and alkyls are involved in nearly all organic transformation caused by transition metal complexes.

Reactions of σ- and w-Bonded Derivatives 46 b. Carbon-Bonded Derivatives Two reaction courses are commonly observed with carbon σ-bonded transition metal complexes: (1) Ligand substitution by a reactant occurs and then the carbon group moves from metal to the ligand (covalent addition) or (2) an external reagent attacks the complex, either at the σ-bonded carbon group (SN2) or at the metal (oxidative addition). For example (34,94b, 94c), CH3COCo(CO)4 -co v [CH3COCo(CO)3] + co H5C2 C2HsC=CC2H5 C2H5 C=CC2H5 CH3COCo(CO)3 C2H5 > = < CH3C O -► products Co(CO)3 C6H5CH2COCo(CO)4 + C6H5NH2 -► QHsCHaCONHCeHs + HCo(CO)4 ci- PEt3 c.

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