By John M. Chalmers, Robert J. Meier

Written through professional individuals from the tutorial and business sectors, this publication offers conventional and sleek ways to polymer characterization and research. The emphasis is on pragmatics, challenge fixing and estate decision; real-world functions offer a context for key suggestions. The characterizations specialise in natural polymer and polymer product microstructure and composition.

  • Approaches molecular characterization and research of polymers from the perspective of problem-solving and polymer estate characterization, instead of from a strategy championing approach
  • Focuses on offering a method to ascertaining the optimal procedure or technique(s) to resolve a problem/measure a estate, and thereby advance an analytical competence within the molecular characterization and research of real-world polymer products
  • Provides history on polymer chemistry and microstructure, discussions of polymer chain, morphology, degradation, and product failure and additive research, and considers the aiding roles of modeling and high-throughput analysis

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25 Polymer Chemistry and Microstructure C CH C C H2 H2 H C CH H2 Cross-link C C H2 H A C CH H2 CH C H2 C CH C C H2 H2 H C H2 CH3 CH C C H C H2 S B S C C H2 H C C H CH3 Figure 10 Examples of crosslinked polymers (A, polyfunctional; B, vulcanised). enzymes, are still not accessible to chemical synthesis at the beginning of the third millennium. Several physical properties of copolymers are directly or indirectly dependent upon the distribution of sequences. The phase behaviour (microphase separation) in block copolymers is linked to the mutual insolubility/ solubility of the sequences.

M. ), Characterisation of Polymers by Thermal Analysis, Elsevier, Amsterdam, 2001. 9 I. Wilson, C. Poole and M. ), Encyclopedia of Separation Science, Academic Press, London, 2000. 10 G. P. Lattimer, Mass Spectrometry of Polymers, CRC Press, Boca Raton, 2001. J. I. ), Polymer Characterisation, Blackie Academic & Professional, Glasgow, 1993. L. , Elsevier Science, New York, 1999. I. ), Polymers: Polymer Characterization and Analysis, Wiley, New York, 1990. I. Kroschwitz, Concise Encyclopedia of Polymer Science and Engineering, Wiley, New York, 1998.

Branching can also give rise to either the so-called ‘‘long-chain branching’’ (LCB) or ‘‘short-chain branching’’ (SCB), see Figure 9. Such terms are of importance particularly for polyethylene as they describe the only3 small ‘‘chemical’’ difference between technologically highly different low-density (LDPE) and linear lowdensity (LLDPE) polyethylenes. Except for polyethylene, the distinction between LCB and SCB is somewhat controversial as it can depend on several characteristics or even on the capacity of the characterisation method itself.

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