By Luogeng Hua

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The parameter kik indicates the strength of the perturbation the scalar coupling constant produces on the ZEEMAN energies Eo(j). The first order perturbation contribution E l ( j ) is added to the zero order ZEEMAN part resulting in Ej = Eo(j) + El(j): for every basis product functionj. 2 The AX Spin System The characteristic first order spin system is based on weak interactions (hik << I), so that truncation of the HAmToNian after the second term El(j) is allowed and the mixing operator on term can be neglected ( X approximation).

6Sofhyare 15 6. g. to identify in the Spectrum Parameters the Number of spectral points edit field. 7. g. g. 500 MHz in the Spectrum Parameters or the list box on the main document window in WIN-DAISY. 0 Key board strokes are given in : 1. Shortcut keys: keeping the control key depressed while another key is pressed. g. to switch the x-axis labels. g. for the run WIN-NMR command. is used to copy the marked item into the WINDOWS Clipboard and to paste contents of the Clipboard at the current cursor placement.

Answer the questions WIN-NMR asks with Yes in order to send also predefined spectral regions defined for the actual multiplet signals. Then the WIN-DAISY program is moved to the WINDOWS foreground. Fig. 12: WIN-NMR multiplet analysis of the aromatic protons of 2-terr-butyl4,6-dinitrophenol. Check it in WIN-DAISY: A new WIN-DAISY document is created. Check the values in the WIN-DAISY Parameter dialog boxes.

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