By Pierre H. Dixneuf, Henri Doucet

The sequence subject matters in Organometallic Chemistry offers severe overviews of analysis ends up in organometallic chemistry. As our realizing of organometallic constitution, homes and mechanisms raises, new methods are opened for the layout of organometallic compounds and reactions adapted to the desires of such different components as natural synthesis, scientific examine, biology and fabrics technology. hence the scope of insurance incorporates a huge variety of issues of natural and utilized organometallic chemistry, the place new breakthroughs are being accomplished which are of importance to a bigger clinical viewers. the person volumes of themes in Organometallic Chemistry are thematic. assessment articles are in general invited via the amount editors. All chapters from themes in Organometallic Chemistry are released OnlineFirst with someone DOI. In references, issues in Organometallic Chemistry is abbreviated as most sensible Organomet Chem and mentioned as a journal.

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References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39 40 41 41 47 49 49 1 Introduction The direct functionalization of a carbon–hydrogen bond was not previously considered as a logical retrosynthetic disconnection mainly due to their high dissociation energy and omnipresence in organic molecules, thus resulting in a low level of efficiency and selectivity. Mainly due to the better understanding of the activation pathway, highly efficient catalytic systems have been developed during the last decades.

Following this ambitious goal, Glorius endeavored on designing such CDCs between two structurally similar heterocyclic scaffolds [146]. The desired cross coupling reaction could be achieved by carefully selecting both coupling partners (typically furans and (benzo)thiophenes), and after an intensive optimization study, the desired transformation delivered a panel of biheteroaryls (14). ð14Þ An additional interesting example of an intramolecular direct arylation occurring via double C–H activation was disclosed in 2013 by Miura [147].

References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39 40 41 41 47 49 49 1 Introduction The direct functionalization of a carbon–hydrogen bond was not previously considered as a logical retrosynthetic disconnection mainly due to their high dissociation energy and omnipresence in organic molecules, thus resulting in a low level of efficiency and selectivity. Mainly due to the better understanding of the activation pathway, highly efficient catalytic systems have been developed during the last decades.

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